I use mdf for a couple of things in the shop (sacrificial fences, jigs, miter bar extensions), but never as a backer. Caution, I can't think of another material that will make more dust when cutting it. It's really just fine sawdust glued together. But it's pretty cheap, almost always flat, doesn't have any grain to worry about. It isn't as strong as wood. Cuts, glues and paints fine. You should prime it for painting especially on cut edges.